One Question (and not meaning to be rude)..
As barometric pressure and temperature changes, the airgap in you vessel will expand and contract. In effect, you vessel will "breathe". In only a short time, all of that inert gas will be gone.
johnT.
Good points but I'm not sure of the breathing concern. Would not this only be true if the gas you used were lighter than air?
The dead space environment is basically dead air with very minimal movement due principally to the barometric breathing you pointed out. Even if the breathing were sufficient enough to pull air in and out past the trap, only the gas at the top would be effected to any extent in a modest sized carboy.
Any heavier gas would simply lay on top of the wine and assure protection even if some oxygen were to find it's way into the dead space. For oxygen to reach the wine, you would need to remove or exchange a significant amount of the shielding gas which will not occur if it is the heavier of the two. Some breathing exchange from the top gas layer "might" occur but this would only serve to exchange air with air, leaving the heavier gas to do it's job.
Now none of this holds true "if" the shielding gas mixes naturally with air upon contact. If this occurs, your description would be absolutely true. So I guess the question is, will argon maintain a separate layer in the dead space or become an equally dispersed component of any air which may find it's way into the dead space environment.
Unfortunately I don't know enough about argon to answer this question. It does exist naturally in the air we breathe as opposed to laying on my living room floor. But it also shields out air during TIG welding implying the two don't readily mix, at least to some extent.
Maybe someone could help us to further understand this issue?
I for one could benefit from using a shielding gas to eliminate air contact during conditioning. I've been using CO2 but have become convinced, CO2 may not remain viable for long periods as it does become absorbed by the wine. I have argon available and can switch to using it without much pain. But I don't want to go down this path unless it's truly effective.
Filling the dead space with wine or water is probably the best approach but unfortunately all my carboys are 6 1/2 gal which makes for a large dead space to fill. Hence I'd like to use a shielding gas.