Wine or grape juice can be especially challenging as the Potassium in grape juice can act as a buffer effectively keeping the pH from changing. If you are trying to adjust the acid on your must you have to go especially slow and add 1/2 what you think it will need. The Potassium will bind with the Tartaric effectively keeping it from changing for quite some time, then it will release it later on and BAM your pH drops like a rock and if you kept adding Tartaric the whole time you are more than likely now way overshot your target acid and pH range.
Always go slow adding acid to must, stir well and let it sit for a few hours, then check it again.