Was this a brand new barrel or did you get it used somewhere? It is an infection though.
Flowers of Wine: Small flecks or blooms of white powder or film may appear on the surface of the wine. If left unchecked, they grow to cover the entire surface and can grow quite thick. They are caused by spoilage yeasts and/or mycoderma bacteria, and if not caught at first appearance will certainly spoil the wine. If caused by yeast, they consume alcohol and give off carbon dioxide gas. They eventually turn the wine into colored water. The wine must be filtered at once to remove the flecks of bloom and then treated with one crushed Campden tablet per gallon of wine. The saved wine will have suffered some loss of alcohol and may need to be fortified with added alcohol (brandy works well) or consumed quickly. If caused by the mycoderma bacteria, treat the same as for a yeast infection. The Campden will probably check it, but the taste may have been ruined. Taste the wine and then decide if you want to keep it. Bacterial infections usually spoil the wine permanently, but early treatment may save it.