No problems adding at the same time. They will not react. Its usually better to add one, stir in then add the second just so they don't clump together and form a blob at the bottom of the carboy. Its interesting that of all the kit makers only RJS includes this additive. Don't expect miracles with the MetaTartaric. It has a claimed effectiveness of up to 12 months but most report crystal formation at 6 months. That can be fine for a white, but a big red won't even be drinkable at 6 mo so why include it?
Either RJS uses much better juice than the other kit makers or their manufacturing process produces it in higher quantities than the other guys (hard to believe). Your probably better off doing a real cold stabilization than banking on this stuff.