I have never made wine from rose petals (I assume you mean rose petal wine and not rosehip wine) but people I have known to do this used the largest roses petals they could find, they gathered them after the rose had bloomed and before the petals turned brown and froze the petals in freezer bags until they had enough for a batch of wine. They used the most fragrant roses they could find and chose the colors based on what they wanted the color of the wine to be. One caution, you should not use any type of pesticide on the roses you plan to harvest for wine. Sorry I can't be of more help.
So how does a rose wine compare to other wines taste-wise?
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