I did mine at 1.002 and another 1.004. I was told by people in the wine club im in to start before it drops below 1.000. Also you may want to add a bit of yeast nutrient too during this process. Good luck.
MLF is caused by bacteria, not yeast. Yeast nutrient isn't advisable for feeding them. I would opt for something specifically formulated for MLF like an Opti-Malo plus. You don't want to give the bad microorganisms food to work with to ruin your wine.
And wine will typically naturally undergo MLF but using a specific strain is more reliable.