Sodium metabisulphite

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how long can I keep this in a bucket before it becomes ineffective. I know that as soon as Star San gets cloudy it’s properties are lessened. Does sodium metabisulphite have a shelf life as well.

Thanks
 
Cloudy Star San does not mean it's ineffective. The pH reading of the solution is the best indicator.
I can make fresh starsan with our tapwater and it's cloudy immediately.

Cloudiness is not desirable but it's not a foolproof indicator either.
 
Cloudy Star San does not mean it's ineffective. The pH reading of the solution is the best indicator.
I can make fresh starsan with our tapwater and it's cloudy immediately.

Cloudiness is not desirable but it's not a foolproof indicator either.


Understood but I think you may be in the monority. Having said that how long does sodium metabisulphite last in storage.
 
If your asking about potassium metabisulphite, we were tought that once mixed, as long as it still has it’s potent smell, it’s good for cleaning. In regards to the powder for use directly in the wine, about 1 year once the package is open. If you meant sodium meta, sorry for the providing the above info.
 
If your asking about potassium metabisulphite, we were tought that once mixed, as long as it still has it’s potent smell, it’s good for cleaning. In regards to the powder for use directly in the wine, about 1 year once the package is open. If you meant sodium meta, sorry for the providing the above info.

I meant once mixed with water how long does it remain effective for sanitizing.
 
I would think it would depend on how it’s stored. I’d bet a 50ppm solution, an inch thick in a 5 gallon bucket would be under 10 within a week or two. A 50ppm in a full spray bottle would probably be 45 ppm after 3 months.

The SO2 is a anti-microbial and an anti-oxidant. Open to the air, the free SO2 will combine with the O2 and reduce in short order.
 
I would think it would depend on how it’s stored. I’d bet a 50ppm solution, an inch thick in a 5 gallon bucket would be under 10 within a week or two. A 50ppm in a full spray bottle would probably be 45 ppm after 3 months.

The SO2 is a anti-microbial and an anti-oxidant. Open to the air, the free SO2 will combine with the O2 and reduce in short order.

How do you measure ppm?
 
how long can I keep this in a bucket before it becomes ineffective. I know that as soon as Star San gets cloudy it’s properties are lessened. Does sodium metabisulphite have a shelf life as well.

Thanks

For sanitation, sodium metabisulfite works fine. The potassium variation is the one that must be used in your wine.

The metabisulfite solution must be acidified to be effective. I use one tbsp of citric acid and one tsp of metabisulfite per gallon of water. This gives a whopping 700+ppm of sulfites that are nearly 100% active because of the low pH.

As far as how long it lasts, that depends on it you return "dirty" solution back your bucket and whether it is open to the air. The sulfites will outgas (why you smell it) and lower the concentration in your container. A spray bottle should be good for over a month. An open bucket probably is only good for the day you are using it.
 
How do you measure ppm?

Ppm = mg / liter
Potassium metabisulfite is 57.6% sulfites.

So 1g of potassium metabisulfite mixed into 5 gallons yields:
0.576 * 1000mg / (5 gal * 3.785 L/gal) = 30.4 ppm sulfites

Note that some of the sulfites become bound to aldehydes, sugar and other compounds.

Also the portion of the sulfites which are active (H2SO3) are a strong function of pH. Much less effective at higher pH.
 
For sanitation, sodium metabisulfite works fine. The potassium variation is the one that must be used in your wine.

I have to take some very small exception to that statement. Sodium metabisulfite can be used in your wine, it will increase the overall sodium in the final product and may lead to a salty taste in the wine, but in a pinch and one time, if you have no potassium and do have sodium. It isn't an absolute must use, but good idea and best practice.
 
For sanitation, sodium metabisulfite works fine. The potassium variation is the one that must be used in your wine.

The metabisulfite solution must be acidified to be effective. I use one tbsp of citric acid and one tsp of metabisulfite per gallon of water. This gives a whopping 700+ppm of sulfites that are nearly 100% active because of the low pH.

As far as how long it lasts, that depends on it you return "dirty" solution back your bucket and whether it is open to the air. The sulfites will outgas (why you smell it) and lower the concentration in your container. A spray bottle should be good for over a month. An open bucket probably is only good for the day you are using it.

Citric acid added to Sodium Metabisulfite for sanitation purposes correct?
 
How do you measure ppm?
It was an investment that was a bit hard on the wallet, a Vinmetrica 300. It is for the reason of not knowing what the efficacy of the cleaning solution after storage that I use StarSan. If I had aciduated water and fresh SO2 and you used it right away, then all should be fine. I would trust my mixture of StarSan weeks later, but wouldn’t have the same confidence with an SO2 solution.
 
During a previous round of these "How long does it last?" Back & Forth discussions I tested 4-5 week old batch of Star San. The pH came in at about 2.7 well within the useful range. One more reason I use it.
 
Sorry that was an incomplete list. The entire section of the code is here. Look at the table in section 24.246 and you'll find potassium metabisulfite
That link didn't go to a specific thing, just the search site. I'll believe you that Sodium metabisulphite isn't allowed in commercial wines. I don't own any, but those laws and list of allowed items don't apply to home winemakers.

Actually from a real computer, not a tablet/phone, the link worked great and there is no mention of Sodium Meta-Bisulphite as reported.
 
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