K-meta (aka: potassium metabisulfite, KMBS, or just sulfite) is useful in winemaking both as a tool / equipment sanitizer when mixed with water, and as an anti-microbial, anti-oxidant when added directly to wine. Some folks also add it to must to ward off any undesirable yeasts, mold spores, bacteria, etc, to prepare for fermentation.
Na-meta is also useful as a sanitizer when mixed with water, and will also act the same way in wine, but may leave your wine tasting salty. Most folks won’t use Na-meta as a wine additive for that reason.
I’ve never used Campden tablets, but they can be made of either the K or Na form of metabisulfite, so check the label. Personally I prefer to keep the powdered form of K-Mets on hand for easy measuring and never fearing putting the Na form in my wine by mistake.